Flexibility and disorder in metal–organic frameworks
نویسندگان
چکیده
منابع مشابه
Interplay between defects, disorder and flexibility in metal-organic frameworks.
Metal-organic frameworks are a novel family of chemically diverse materials, which are of interest across engineering, physics, chemistry, biology and medicine-based disciplines. Since the development of the field in its current form more than two decades ago, priority has been placed on the synthesis of new structures. However, more recently, a clear trend has emerged in shifting the emphasis ...
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We formulate a concise deformation theory for periodic bar-and-joint frameworks in Rd and illustrate our algebraic–geometric approach on frameworks related to various crystalline structures. Particular attention is given to periodic frameworks modelled on silica, zeolites and perovskites. For frameworks akin to tectosilicates, which are made of one-skeleta of d-dimensional simplices, with each ...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2016
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c6dt90026g